Synthesis and Catalytic Applications of Polymetallic Complexes Composed of 1,10-Phenanthroline and NHC Ligand Systems
Project no. 26294 · Status: Kapanmış · 2023
Summary
<p>In this project, mono ruthenium p-cymene complexes consisting of different 1,10-</p><p>Phenanthroline and NHC ligand systems that are not included in the literature were prepared.</p><p>The structures of the prepared ligands and ruthenium complexes were elucidated by NMR and</p><p>FT-IR spectroscopy. The catalytic activities of the synthesized Ru(II) complexes were</p><p>investigated. According to the results obtained from this project, it was aimed to determine</p><p>which group was active and to continue with new projects in subsequent derivatization</p><p>studies. New Ru(II) complexes were added to the literature and it was aimed to publish the</p><p>outputs that will be generated as a result of the project in high impact value articles.</p><p>The project consists of three parts. The first part covers information on carbenes, Nheterocyclic</p><p>carbenes, 1,10-phenanthrolines, 1,10 phenanthroline based NHC metal</p><p>complexes in the literature and their catalytic applications. The second part describes</p><p>experimental studies. The third part provides information on the synthesis, characterization</p><p>and catalytic studies of ligands and Ru complex. The reactions of the synthesized ruthenium</p><p>complexes were carried out starting from 5-bromo-1,10-phenanthroline.</p>