Tuning the selectivity in iridium-catalyzed acceptorless dehydrogenative coupling of primary alcohols
Makaleler > Tam Makale · 2022
Yazarlar: Nihal S. Tabasi, Sertaç Genç, Derya GÜLCEMAL
Organic & Biomolecular Chemistry, Uluslararası, Scopus, 2022, cilt 20, ss 6582-6592
DOI: 10.1039/d2ob01142e
Özet
both homo- and cross-β-alkylation of the alcohols) in the presence of an N-heterocyclic carbene iridium(I) catalyst was developed under aerobic conditions. The product selectivity can be easily tuned among the products with a single catalyst through simple modification of the reaction conditions, such as the catalyst and base amounts, the choice of base, and the reaction temperature.