Application of experimental design on determination of aluminum content in saline samples by adsorptive cathodic stripping voltammetry
Makaleler > Tam Makale · 2013
Yazarlar: Sinan YILMAZ, Betul Ozturk, Durmua Ozdemir, Ahmet Emin Eroglu, Fatma Nil ERTAŞ
IYTE GCRIS Database (Izmir Institute of Technology), SCI Expanded İndekslerine Giren Dergi, Uluslararası, 2013, cilt 37, ss 316-324
DOI: 10.3906/kim-1204-56
Özet
Adsorptive cathodic stripping voltammetric determination of aluminum at ng mL-1 levels in salt samples based on the metal complexation with Calcon (1-(2-hydroxynaphthylazo)-2 naphthol-4-sulfonic acid) and the subsequent adsorptive deposition onto a hanging mercury drop electrode was studied. Central composite design was used as a design method. Several chemical and instrumental parameters (pH, ligand concentration, deposition time, deposition potential, and complexing time) were involved in the experimental design. Analytical parameters such as repeatability, linearity, and accuracy were also investigated and the detection limit was found as 0.32 ng mL-1.