Highly Efficient Organic UV Photodetectors Based on Polyfluorene and Naphthalenediimide Blends: Effect of Thermal Annealing

Articles > Article · 2012

Authors: Gorkem Memisoglu, Canan Varlikli

International Journal of Photoenergy, International, WoS, 2012, vol 2012, pp 1-11

DOI: 10.1155/2012/936075

Summary

A solution-processed organic ultraviolet photodetector (UV-PD) is introduced. The active layer of the UV-PD consists of poly(9,9-dioctyl fluorenyl-2,7–yleneethynylene) (PFE) and N,N′-bis-n-butyl-1,4,5,8- naphthalenediimide (BNDI) with a weight ratio of 3 : 1 in chloroform. The effect of thermal annealing on the device properties was investigated from room temperature to 8 0 ∘ C . The full device structure of ITO/PEDOT:PSS/PFE:BNDI (3 : 1)/Al gave responsivity of 410 mA/W at −4 V under 1 mW/cm2 UV light at 368 nm when 6 0 ∘ C of annealing temperature was used during its preparation. The devices that were annealed over the crystallization temperature of PFE showed a charge transfer resistance increase and a mobility decrease.

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