Investigation of Photochemical Reactions of some Metal Carbonyls with N '-(2-Hydroxy-6-Methylbenzylidene)Methanesulfonohydrazide and 5-Methyl-2-Hydroxyacetophenonemethanesulfonylhydrazone
Makaleler > Tam Makale · 2021
Yazarlar: Sema SERT
ACTA CHIMICA SLOVENICA, SCI Expanded İndekslerine Giren Dergi, Uluslararası, 2021, cilt 68, ss 483-487
Özet
Eight new complexes, [M(CO)(5)(5msalmsh)] [M=Cr;(1a), Mo;(2a); W(3a)] , [Re(CO)(4)Br(5msalmsh)] (4a), [M(CO)(5)(5mafmsh)] [M=Cr;(1b), Mo;(2b); W(3b)], [Re(CO)(4)Br(5mafmsh)] (4b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO)(6)] (M=Cr, Mo, W) and [Re(CO)(5)Br] with N'-(2-Hydroxy-6-Methylbenzylidene) Methanesulfonohydrazide (5msalmsh) and 5-methyl-2-hydroxyacetophenonemethanesulfonylhydrazone (5mafmsh). The complexes have been characterized by elemental analysis, LC-MS, FT-IR, H-1 NMR spectroscopy. Spectroscopic studies show that 5msalmsh and 5mafmsh behave monodentate ligand and coordinate via an imine N donor atom to the central metal atom in (1a)-(4a) and (1b)-(4b).