Electrochemical removal of arsenic and remediation of drinking water quality

Makaleler > Tam Makale · 2021

Yazarlar: Özge SÜRÜCÜ

Desalination and Water Treatment, SCI Expanded İndekslerine Giren Dergi, Uluslararası, Wos, 2021, cilt 216, ss 246-251

DOI: 10.5004/dwt.2021.26808

Özet

<p><span style="left: 181.667px; top: 578.451px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.10141);">Arsenic is one of the most abundant elements on the earth and possesses metallic as well as </span><span style="left: 181.667px; top: 594.615px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.06746);">nonmetallic properties. Besides arsenic is very toxic and carcinogenic, it is found in nature both </span><span style="left: 181.667px; top: 610.78px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.14098);">naturally and anthropogenically. Inorganic arsenic species existing in water are arsenite (As</span><span style="left: 773.657px; top: 610.391px; font-size: 8.25917px; font-family: serif; transform: scaleX(0.957312);">3+</span><span style="left: 782.082px; top: 610.785px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.16607);">) and </span><span style="left: 181.67px; top: 626.949px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.10766);">arsenate (As</span><span style="left: 263.574px; top: 626.558px; font-size: 8.25917px; font-family: serif; transform: scaleX(0.957312);">5+</span><span style="left: 271.998px; top: 626.951px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.08925);">). Arsenic toxicity is a global problem because arsenic contamination is naturally </span><span style="left: 181.672px; top: 643.115px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.14272);">coming from water resources. The maximum admissible concentration of arsenic must not exceed </span><span style="left: 181.672px; top: 659.28px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.02);">10</span><span style="left: 199.267px; top: 659.28px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.17997);">µg</span><span style="left: 219.737px; top: 659.28px; font-size: 14.1667px; font-family: serif;">L</span><span style="left: 228.528px; top: 658.891px; font-size: 8.25917px; font-family: serif; transform: scaleX(1.01907);">–1</span><span style="left: 236.953px; top: 659.285px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.11335);">, so the determination of the total arsenic amount regardless of its species is very important. </span><span style="left: 181.66px; top: 675.449px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.05679);">In this work, the presence of arsenic was electrochemically determined using cyclic, square wave </span><span style="left: 181.66px; top: 691.613px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.10485);">and differential pulse voltammetry, and a spectroscopic determination method including induc-</span><span style="left: 181.66px; top: 707.777px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.10022);">tively coupled plasma-mass spectrometry (ICP-MS) was applied. A combination of ICP-MS as a sen-</span><span style="left: 181.66px; top: 723.941px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.14356);">sitive, multi-element capable and reliable method with electrochemistry as a simple, cost-efficient </span><span style="left: 181.66px; top: 740.105px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.07328);">and powerful method was performed to determine and remove arsenic for the first time. Newly </span><span style="left: 181.66px; top: 756.27px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.13784);">modified nano-dimensional surfaces were developed to obtain specific arsenic behavior and effec-</span><span style="left: 181.66px; top: 772.434px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.0596);">tive electrodeposition of arsenic in the removal process. With the water supply research, regional </span><span style="left: 181.66px; top: 788.598px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.104);">differences in drinking waters were discovered, and different kinds of drinking water samples </span><span style="left: 181.66px; top: 804.762px; font-size: 14.1667px; font-family: serif; transform: scaleX(1.13367);">were put into a common form in terms of drinkable, arsenic-free, high-grade standards.</span></p>

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