Zinc(II) and Cadmium(II) Salphen Catalyzed Alkylation Reactions to Form α-Alkylated Ketones
Makaleler > Tam Makale · 2022
Yazarlar: Salih GÜNNAZ
Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Diğer Kurumların Hakemli Dergileri, Uluslararası, TR Dizin (Ulakbim), 2022, cilt 15, ss 788-801
DOI: 10.18185/erzifbed.1201394
Özet
The zinc (II) and cadmium (II)-salphen catalyzed α-alkylation of ketones with primary alcohols is reported. Various α-alkylated ketones were obtained in good yields through a borrowing hydrogen strategy by using 1 % of catalysts and a catalytic amount of NaOH (10 mol%) as the base under air atmosphere. All synthesized compounds were characteized by 1H and 13C NMR.