New Cu(II) coordination polymer by chiral tridentate Schiff base ligand
Makaleler > Tam Makale · 2017
Yazarlar: Amel MESSAI, Melek Duygu BİLGE, Metin BİLGE, Cemal PARLAK
JOURNAL OF MOLECULAR STRUCTURE, SCI Expanded İndekslerine Giren Dergi, Uluslararası, 2017, cilt 1137, ss 349-353
DOI: 10.1016/j.molstruc.2017.02.046
Özet
The present research reports the synthesis, X-ray, magnetic and electronic properties for novel coordination polymer based upon copper (II) with chiral tridentate Schiff base ligand synthesized at condensation of acetylacetone and L-leucine amino acid. The investigation was also conducted by quantum mechanical calculations. The large energy gap indicates a high kinetic stability. Magnetic measurement gives predominant antiferromagnetic interactions within the chain. Results reveals further insight into copper(II) chiral tridentate Schiff base complexes. (C) 2017 Elsevier B.V. All rights reserved.