Palladium-catalysed reactions of conjugated enyne oxiranes with organoborons: A diastereoselective method of the synthesis of 2,4,5-trienol derivatives

Makaleler > Tam Makale · 2018

Yazarlar: Firat Ziyanak, Melih Kus, Leman ALKAN, Levent Artok

TETRAHEDRON, SCI Expanded İndekslerine Giren Dergi, Uluslararası, 2018, cilt 74, ss 3652-3662

DOI: 10.1016/j.tet.2018.05.030

Özet

A palladium-catalysed reaction of conjugated enyne oxiranes with organoboron reagents is described. This method allows aryl-substituted vinylallenes containing a hydroxyl group on the allylic position to be synthesized, with good diastereomeric ratios, under mild conditions. (C) 2018 Elsevier Ltd. All rights reserved.

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