Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W)] with N , N′ -bis(salicylidene)-1,2-bis- ( o -aminophenoxy)ethane
Makaleler > Tam Makale · 2006
Yazarlar: Elif Subasi, Hamdi Temel, Ozan S. Senturk, Fadime Ugur
Journal of Coordination Chemistry, Uluslararası, Wos, 2006, cilt 59, ss 1807-1811
DOI: 10.1080/00958970600571703
Özet
The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1–3.