The synthesis and structural characterization of a N -heterocyclic carbene-substituted palladacycle
Makaleler > Tam Makale · 2006
Yazarlar: Aytaç Gürhan Gökçe, M. Emın Günay, Muhıttın Aygün, Bekır Çetınkaya, Orhan Büyükgüngör
Journal of Coordination Chemistry, Uluslararası, Wos, 2006, cilt 60, ss 805-813
DOI: 10.1080/00958970600923334
Özet
Aytaç Gürhan Gökçea*, M. Emın Günayb, Muhıttın Aygüna, Bekır Çetınkayac & Orhan Büyükgüngörd a Department of Physics , Dokuz Eylul University , Buca–35160, ızmir, Turkey b Department of Chemistry , Adnan Menderes University , Aydın–09010, Turkey c Department of Chemistry , Ege University , Bornova–35100, İzmir, Turkey d Department of Physics , Ondokuz Mayıs University , Samsun–55139, Turkey * E-mail: aytac.gokce@deu.edu.tr Reaction of {[Pd(dmba)(μ-Cl)]2} (dmba = (CH3)2NCH2C6H4) with an in situ generated N-heterocyclic carbene (NHC = 1,3-dimesitylimidazolidin-2-ylidene) afforded crystals containing [chloro-(1,3-dimesitylimidazolidin-2-ylidene)(N,N-dimethylaminobenzyl-C1,N)palladium(II)] (VII). Molecular and crystal structures of the title compound have been determined by single crystal X-ray diffraction technique. Complex VII crystallizes in space group P 1, with a = 13.685(3) Å, b = 13.590(2) Å, c = 16.229(3) Å, α = 87.162(13)°, β = 70.514(15)°, γ = 84.153(16)°, Z = 4, D Calcd = 1.367 g cm−3. There are two independent molecules in the asymmetric unit.