Reduction Reactions with NHC-bearing Complexes
Kitapta bölümler > Diğer · 2010
Yazarlar: Bekir Çetinkaya
N-Heterocyclic Carbenes, Diğer, Royal Society of Chemistry, B, Uluslararası, 2010, ss 366-398, ,
DOI: 10.1039/9781849732161-00366
Özet
This Chapter summaries the studies conducted on the reduction of multiple-bonded organic compounds in the presence of NHC–metal complexes as homogeneous catalysts. The following reactions have been examined: hydrogenation, transfer hydrogenation, hydrosilylation and hydroboration. Reports of the application of hydrosilylation and hydroboration in the synthesis of complex organic molecules and via subsequent cleavage of Si−C or B−C bonds are also discussed.