Vitamin B1-based thiazol-2-ylidene–Ru( ii ) complexes: recyclable transfer hydrogenation catalysts in water

Articles > Article · 2024

Authors: Rafet Kılınçarslan, Hayriye Tuncer, Namık Özdemir, Bekir Çetinkaya

Dalton Transactions, International, WoS, 2024, vol 53, pp 9192-9197

DOI: 10.1039/d4dt00445k

Summary

In order to develop recyclable catalyst in water, vitamin B1 based Ru( ii )-NHC complexes (2–4) were synthesized and evaluated for transfer hydrogenation of ketones and aldehydes with an azeotropic mixture of HCOOH/Et 3 N in water. The complex,4 exhibited excellent catalytic activity and recyclability.

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