Synthesis and vibrational spectroscopic analysis of some Hofmann type clathrates
Makaleler > Tam Makale · 2011
Yazarlar: Cemal PARLAK, Mustafa Senyel
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, SCI Expanded İndekslerine Giren Dergi, Uluslararası, 2011, cilt 82, ss 383-388
DOI: 10.1016/j.saa.2011.07.067
Özet
New Hofmann type clathrates in the form of M(pp)(2)Ni(CN)(4)center dot 2G (where pp = 1-phenylpiperazine, G = 1,4-dioxane and M = Ni, Co or Cd) have been prepared in powder form and their FT-IR and FT-Raman spectra are reported. The results suggest that the present compounds are similar in structure to the Hofmann type clathrates and their structures consist of conjugated polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(infinity) with the pp bound to the metal (M) atom. (C) 2011 Elsevier B.V. All rights reserved.