C–C coupling formation using nitron complexes
Makaleler > Tam Makale · 2020
Yazarlar: Mehmet Sevim, Serdar Batıkan KAVUKCU, Armağan KINAL, Onur Sahin, Hayati TÜRKMEN
Dalton Transactions, SCI Expanded İndekslerine Giren Dergi, Uluslararası, Wos, 2020, cilt 49, ss 16903-16915
DOI: 10.1039/d0dt02937h
Özet
A series of RuII (1), RhIII (2), IrIII (3, 4), IrI (5) and PdII (6-9) complexes of the 'instant carbene' nitron were prepared and characterized by 1H- and 13C-NMR, FT-IR and elemental analysis. The molecular structures of complexes 1-4 and 6 were determined by X-ray diffraction studies. The catalytic activity of the complexes (1-9) was evaluated in alpha(α)-alkylation reactions of ketones with alcohol via the borrowing hydrogen strategy under mild conditions. These complexes were able to perform this catalytic transformation in a short time with low catalyst and base amounts under an air atmosphere. Also, the PdII-nitron complexes (6-9) were applied in the Suzuki-Miyaura C-C coupling reaction and these complexes successfully initiated this reaction in a short time (30 minutes) using the H2O/2-propanol (1.5 : 0.5) solvent system. The DFT calculations revealed that the Pd0/II/0 pathway was more preferable for the mechanism.