VIBRATIONAL SPECTROSCOPIC INVESTIGATION OF SOME HOFMANN TYPE CLATHRATES: M(4-PHENYLPYRIDINE)(2)Ni(CN)(4)center dot 2G (M = Ni, Co AND Cd, G=1,4-DIOXANE)
Makaleler > Tam Makale · 2010
Yazarlar: Cemal PARLAK
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, SCI Expanded İndekslerine Giren Dergi, Uluslararası, 2010, cilt 24, ss 375-381
Özet
New Hofmann type clathrates in the form of M(4-Phpy)(2)Ni(CN)(4)center dot 2G (where 4-Phpy = 4-phenylpyridine, G = 1,4-dioxane and M = Ni, Co and Cd) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that these compounds are similar in structure to the Hofmann type clathrates and their structures consist of polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(infinity) with the 4-Phpy bound to the metal (M) atom.