Structural properties of sputtered amorphous Ga1-xPxfilms

Articles > Article · 2000

Authors: N Elgun, S J Gurman, E A Davis

Journal of Physics: Condensed Matter, International, WoS, 2000, vol 12, pp 4723-4733

DOI: 10.1088/0953-8984/12/22/305

Summary

a-Ga 1- x P x (0.5⩽ x ⩽1) films have been prepared by r.f. sputtering. The local structure and bonding configurations in these films have been investigated by extended x-ray absorption fine structure (EXAFS) and infrared (IR) spectroscopy measurements. The results show that the network of the films is chemically ordered over the composition range studied. They also show that excess P atoms are incorporated with fourfold coordination into the network for x <0.8. This indicates substitutional alloying, which in turn suggests the dopability of the material.

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