Dichlorido[1-(2-methylbenzyl)-3-(η6-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate
Makaleler > Tam Makale · 2009
Yazarlar: Hakan Arslan, Don VanDerveer, Sedat Yaşar, İsmail Özdemir, Bekir Çetinkaya
Acta Crystallographica Section E Structure Reports Online, Uluslararası, Wos, 2009, cilt 65, ss m243-m244
DOI: 10.1107/s160053680900350x
Özet
The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octa-hedrally coordinated Ru center with the arene occupying three sites. Two Ru-Cl bonds and one Ru-carbene bond complete the distorted octa-hedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C(6)H(2)(CH(3))(3) arene group by a CH(2) bridge. This leads to a system with very little apparent strain. A dichloro-methane solvent mol-ecule completes the crystal structure. Further stabilization is accomplished via C-H⋯N and C-H⋯Cl interactions.