[Bis(diphenylphosphino)methane-kappa P-2,P '][bis(diphenylthiophosphinyl)methane-kappa S-2,S ']-platinum(II) bis(perchlorate) acetone solvate
Articles > Article · 2005
Authors: Leman ALKAN, Sevil İRİŞLİ
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, Journal Indexed in SCI Expanded, International, 2005, vol 61, pp m2706-m2708
DOI: 10.1107/s1600536805038304
Summary
The title complex, [Pt(C25H22P2)(C25H22P2S2)](ClO4)(2)center dot C3H6O or [Pt(dppm)(dppmS(2))](ClO4)(2)center dot C3H6O, where dppmS(2) is bis(diphenylthiophosphinyl) methane and dppm is bis( diphenylphosphino) methane, is the first example of a platinum(II) complex containing both dppm and dppmS(2) ligands. In the cation, the dppm ligand forms a non-planar four-membered chelate ring, while the dppmS(2) ligand forms a six-membered chelate ring with twist-boat conformation.