[Bis(diphenylphosphino)amine-κ2P,P′][1,3-bis(diphenylphosphino)propane-κ2P,P′]platinum(II) dichloride dichloromethane solvate

Articles > Article · 2005

Authors: Sev˙il İrişli, Ayten Şen

Acta Crystallographica Section E Structure Reports Online, International, WoS, 2005, vol 61, pp m2097-m2099

DOI: 10.1107/s1600536805029880

Summary

The title complex, [Pt(C24H21NP2)(C27H26P2)]Cl2·CH2Cl2 or [Pt(dppa)(dppp)]Cl2·CH2Cl2, where dppa is bis­(diphenyl­phos­phino)amine and dppp is 1,3-bis­(diphenyl­phos­phino)­propane, has two different chelate rings. The PtII atom has a distorted square-planar geometry. The six-membered chelate ring of dppp has a chair conformation. There is a hydrogen bond between the dppa N—H group and a Cl− counter-ion.

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