Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone
Makaleler > Tam Makale · 2019
Yazarlar: Sema SERT
Natural and Applied Sciences Journal, Uluslararası, 2019, cilt 2, ss 27-31
Özet
The new complexes, [M(CO)5(msh4)] (Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone(msh4) .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur.