Ruthenium(II) complexes derived from 2‐phenylthiazoline‐4‐carboxylic acid: structure and catalytic activity for transfer hydrogenation reaction
Makaleler > Tam Makale · 2016
Yazarlar: Serpil DENİZALTI, Betul Sen, Aytac Gurhan Gokce, BEKİR ÇETİNKAYA
Applied Organometallic Chemistry, SCI Expanded İndekslerine Giren Dergi, Uluslararası, Wos, 2016, cilt 30, ss 373-377
DOI: 10.1002/aoc.3442
Özet
Piano‐stool ([(p‐cymene)Ru(thz)Cl], 2) and six‐coordinated ([Ru(thz)2(PPh3)2], 3) ruthenium complexes derived from 2‐phenylthiazoline‐4‐carboxylic acid (Hthz, 1) were synthesized for the first time, and fully characterized using conventional methods. Also, the molecular structure of complex 3 was determined using X‐ray analysis. These complexes were evaluated as catalysts for transfer hydrogenation of carbonyl compounds in the presence of isopropyl alcohol and KOtBu. Complex 2 was found to be more active than 3 in transfer hydrogenation. Copyright © 2016 John Wiley & Sons, Ltd.