Heterogeneous Fenton-like Degradation of Orange II in Water Using FeZSM-5 Zeolite Catalyst
Makaleler > Tam Makale · 2012
Yazarlar: Emre Bolova, Gönül Gündüz, Meral DÜKKANCI
International Journal of Chemical Reactor Engineering, SCI Expanded İndekslerine Giren Dergi, Uluslararası, Wos, 2012, cilt 10
Özet
In this study, Fenton-like degradation of Orange II in water was investigated over an FeZSM-5 zeolite catalyst prepared by ion exchange. A color removal of 99.99 % and a COD elimination of 55.0 % were achieved after a reaction time of 2h at 266.7 mM H2O2 at 323 K for 0.05 g/dm3 of Orange II solution at a pH around 7. Initial decolorization rate was described by an equation of -rAo = 6.4x103 e-30.7/RT COII,o CH2O2,o0.3 where R is in kJ/mol. No significant decay in decolorization efficiency of the used catalyst was observed.