Synthesis of novel palladium N‐heterocyclic‐carbene complexes as catalysts for Heck and Suzuki cross‐coupling reactions

Articles > Article · 2006

Authors: Ismail Özdemir, Murat Yiǧit, Engin Çetinkaya, Bekir Çetinkaya

Applied Organometallic Chemistry, International, WoS, 2006, vol 20, pp 187-192

DOI: 10.1002/aoc.1038

Summary

Abstract Novel palladium‐1,3‐dialkylperhydrobenzimidazolin‐2‐ylidene (2a–c) and palladium‐1,3‐dialkylimidazolin‐2‐ylidene complexes (4a,b) have been prepared and characterized by C, H, N analysis, 1H‐NMR and 13C‐NMR. Styrene or phenylboronic acid reacts with aryl halide derivatives in the presence of catalytic amounts of the new palladium‐carbene complexes, PdCl2(1,3‐dialkylperhydrobenzimidazolin‐2‐ylidene) or PdCl2(1,3‐dialkylimidazolin‐2‐ylidene) to give the corresponding CC coupling products in good yields. Copyright © 2006 John Wiley & Sons, Ltd.

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