COORDINATION OF COPPER AND SILVER BY [CO2(MU-C2(CH2SCH2CH2)2S)(CO)6]
Articles > Article · 1993
Authors: F DEMIRHAN, Sevil İRİŞLİ, SN SALEK, OS SENTURK, MJ WENT, JC JEFFERY
JOURNAL OF ORGANOMETALLIC CHEMISTRY, Journal Indexed in SCI Expanded, International, 1993, vol 453, pp C30-C31
DOI: 10.1016/0022-328x(93)83134-h
Summary
The thiamacrocycle [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{mu-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine substitution.