Structure and Luminescent Properties of the 4-Arylidene-2-Aryl-5-Oxazolones(Azlactones)In Solution and Crystalline State
Makaleler > Tam Makale · 1999
Yazarlar: S. Icli, A. O. Doroshenko, S. Alp, N. A. Abmanova, S. I. Egorova, S. T. Astley
Spectroscopy Letters, Uluslararası, Wos, 1999, cilt 32, ss 553-569
DOI: 10.1080/00387019909350006
Özet
Experimental and theoretical evaluations have proven that very low fluorescence quantum yields of azlactones in solution are not caused by an efficient inter system crossing from S1*(ππ) to T*(nπ) states, but rather from solvation and steric effects, that result in non-planarity of the molecular system. High fluorescence quantum yields in the solid state are attributed to the planarity of the azlactone molecule upon packing into the crystal lattice. Supporting evidence was found upon observation of the excited state proton transfer (ESIPT) bands of fluorescence emissions of o-hydroxyarylidene derivatives. The photoinstability of azlactones in liquid states are attributed to photochemical E-Z isomerization and cleavage of the hetero ring α to the carbonyl group.