Active ruthenium-(N-heterocyclic carbene) complexes for hydrogenation of ketones

Articles > Article · 2006

Authors: Murat Yi??it, Beyhan Yi??it, İsmail Özdemir, Engin Çetinkaya, Bekir Çetinkaya

Applied Organometallic Chemistry, International, WoS, 2006, vol 20, pp 322-327

DOI: 10.1002/aoc.1054

Summary

Four ruthenium-N-heterocyclic carbene complexes (3–6) have been prepared and the new compounds characterized by C, H, N analyses, 1H-NMR and 13C-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3–6 in the presence of t-BuOK. Copyright © 2006 John Wiley & Sons, Ltd.

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